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Provedor de dados:  Scientia Agricola
País:  Brazil
Título:  Biosolids and heavy metals in soils
Autores:  Silveira,Maria Lucia Azevedo
Alleoni,Luís Reynaldo Ferracciú
Guilherme,Luiz Roberto Guimarães
Data:  2003-12-01
Ano:  2003
Palavras-chave:  Sewage sludge
Adsorption
Speciation
PH
Organic matter
Resumo:  The application of sewage sludge or biosolids on soils has been widespread in agricultural areas. However, depending on their characteristics, they may cause increase in heavy metal concentration of treated soils. In general, domestic biosolids have lower heavy metal contents than industrial ones. Origin and treatment method of biosolids may markedly influence their characteristics. The legislation that controls the levels of heavy metal contents in biosolids and the maximum concentrations in soils is still controversial. In the long-term, heavy metal behavior after the and of biosolid application is still unknown. In soils, heavy metals may be adsorbed via specific or non-specific adsorption reactions. Iron oxides and organic matter are the most important soil constituents retaining heavy metals. The pH, CEC and the presence of competing ions also affect heavy metal adsorption and speciation in soils. In solution, heavy metals can be present either as free-ions or complexed with organic and inorganic ligands. Generally, free-ions are more relevant in environmental pollution studies since they are readily bioavailable. Some computer models can estimate heavy metal activity in solution and their ionic speciation. Thermodynamic data (thermodynamic stability constant), total metal and ligand concentrations are used by the GEOCHEM-PC program. This program allows studying heavy metal behavior in solution and the effect of changes in the conditions, such as pH and ionic strength and the application of organic and inorganic ligands caused by soil fertilization.
Tipo:  Info:eu-repo/semantics/article
Idioma:  Inglês
Identificador:  http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0103-90162003000400029
Editor:  São Paulo - Escola Superior de Agricultura "Luiz de Queiroz"
Relação:  10.1590/S0103-90162003000400029
Formato:  text/html
Fonte:  Scientia Agricola v.60 n.4 2003
Direitos:  info:eu-repo/semantics/openAccess
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